I-Zirconium tetrachloride Zrcl4

1,Isingeniso esifushane:

Ngezinga lokushisa lekamelo,I-Zirconium tetrachloride i-crystalline powder emhlophe enesakhiwo se-lattice sohlelo lwe-cubic crystal. Izinga lokushisa le-sublimation lingu-331 ℃ kanti indawo encibilikayo ingu-434 ℃. I-molecule ye-zirconium tetrachloride enegesi inesakhiwo se-tetrahedral. Esimeni esiqinile, i-zirconium tetrachloride ihlotshaniswa nenye ukuze yenze uhlaka lweketango elixubile eline-ZrCl6 octahedron njengeyunithi.

Amakhemikhali e-zirconium tetrachloride afana ne-titanium tetrachloride, kodwa umsebenzi wayo ubuthakathaka kancane kune-titanium tetrachloride. I-Zirconium tetrachloride i-hydrolyzed kalula futhi ingase ikhiqize i-zirconium oxychloride ne-hydrochloric acid ezixazululweni ezinamanzi noma emoyeni onomswakama. I-Zirconium tetrachloride inyibilika kuma-solvents amaningi e-organic, njengotshwala, i-ether, njalonjalo. I-Zirconium tetrachloride ingasabela ngezinsimbi ezisebenzayo njenge-sodium, i-magnesium, i-calcium, njll., futhi ingancishiswa ibe yizinsimbi noma i-valent chloride ephansi kuye ngezimo ezihlukene. I-ZrCl4 iyisandulela samakhemikhali amaningi e-zirconium. Ingasetshenziselwa izinhloso ezithile ezahlukahlukene, ikakhulukazi igxile kusayensi yezinto zokwakha, noma njenge-catalyst. Ingasabela ngokuqinile emanzini, ine-hygroscopicity eqinile, futhi i-hydrolyzed kalula.

Ukubukeka Nencazelo:

Inombolo yeCas:10026-11-6

I-Zirconium tetrachlorideiyikristalu emhlophe, ecwebezelayo noma impushana ethambekele ekubeni noshukela.

Igama lesiShayina: zirconium tetrachloride

Ifomula yekhemikhali:Zrcl4

Isisindo se-molecule: 233.20

Ukuminyana: ukuminyana okuhlobene (amanzi=1) 2.80

Umfutho we-Steam: 0.13kPa (190 ℃)

Iphuzu elincibilikayo: ＞ 300 ℃

Indawo yokubilisa: 331 ℃/sublimation

Imvelo:

Ukunyibilika: Incibilika emanzini abandayo, i-ethanol, i-ether, ayincibiliki ku-benzene, i-carbon tetrachloride, ne-carbon disulfide. I-Zirconium tetrachloride ikhipha intuthu emoyeni onomswakama futhi ithola i-hydrolysis eqinile lapho ithintana namanzi. I-hydrolysis ayiphelele, futhi umkhiqizo we-hydrolysis yi-zirconium oxychloride:

ZrCl4+H2O─→ZrOCl2+2HCl

I-2.Ukuhlelwa kanye nenqubo yokukhiqiza ye-zirconium tetrachloride

Ukuhlukaniswa kwe-zirconium tetrachloride

I-zirconium tetrachloride engahluziwe yezinga lezimboni, i-zirconium tetrachloride ecwengiwe yezinga lezimboni, izinga le-athomu elingahluziwe le-zirconium tetrachloride, izinga le-athomu elicwengekileyo le-zirconium tetrachloride, kanye ne-electronic grade zirconium tetrachloride.

1) Umehluko phakathi kwebanga lezimboni kanye nezinga le-athomu i-zirconium tetrachloride

I-Industrial grade zirconium tetrachloride yokuhlukaniswa kwe-zirconium ne-hafnium; Izinga lamandla e-athomu le-zirconium tetrachloride liye labhekana nenqubo yokuhlukanisa i-zirconium hafnium.

2) Umehluko phakathi kwe-zirconium tetrachloride engahluziwe necwengiwe

I-zirconium tetrachloride engahluziwe ayizange ihlanzwe ukuze ikhiphe insimbi; I-zirconium tetrachloride ecwengekile iye yabhekana nenqubo yokuhlanza nokukhipha insimbi.

3) I-Electronic grade zirconium tetrachloride

Isetshenziswa kakhulu embonini ye-elekthronikhi.

Inqubo yokukhiqiza i-zirconium tetrachloride

Inqubo 1

I-Zircon sand desilication i-zirconia chlorination yezinga lezimboni i-zirconium tetrachloride yokuhlanza ibanga lezimboni i-zirconium tetrachloride enhle;

Inqubo 2

Isihlabathi se-Zircon - ukuncibilika kwe-alkali - i-zirconium oxychloride - ukuhlukaniswa kwe-zirconium hafnium - izinga le-athomu lamandla i-zirconia - i-chlorination - izinga le-athomu lamandla ama-coarse zirconium tetrachloride - izinga lamandla e-athomu elihle zirconium tetrachloride;

Inqubo 3

Isihlabathi se-Zircon - i-chlorination - ibanga lezimboni ze-zirconium tetrachloride - ukuhlanzwa kwebanga lezimboni ze-zirconium tetrachloride enhle;

Inqubo 4

Isihlabathi se-Zircon - i-desilication zirconia - i-chlorination - i-industrial grade crude zirconium tetrachloride - ukuhlanzwa - ibanga lezimboni elicwengisiswe i-zirconium tetrachloride - ukuhlukaniswa kwe-pyrometallurgical ye-zirconium ne-hafnium - izinga le-athomu elicwengekile le-zirconium tetrachloride.

Inqubo 5

Isihlabathi se-Zircon - i-chlorination - i-industrial grade coarse zirconium tetrachloride - ukuhlanzwa - i-industrial grade zirconium tetrachloride Ukuhlukaniswa komlilo kwe-zirconium ne-hafnium - izinga le-athomu elicwengekile i-zirconium tetrachloride.

Izidingo zekhwalithi zei-zirconium tetrachloride

Okuqukethwe ukungcola: i-hafnium, insimbi, i-silicon, i-titanium, i-aluminium, i-nickel, i-manganese, i-chromium;

Okuqukethwe okuyinhloko: i-zirconia noma i-zirconia yensimbi;

Ubumsulwa: 100% susa ukuhlanzeka kokungcola;

Okuqukethwe kwezinto ezingancibiliki;

 I-Electronic grade zirconium tetrachloride

Ubumsulwa 99.95%

Izinga lezimboni ze-zirconium tetrachloride

1) I-tetrachloride ye-zirconium engahluziwe

2) I-tetrachloride ecwengekile ye-zirconium

I-Atomic Energy Level Zirconium Tetrachloride

1) I-tetrachloride ye-zirconium engahluziwe

2) I-tetrachloride ecwengekile ye-zirconium

3 Abanye

3.1 Izinto ezithinta ukukhiqizwa kwe-zirconium tetrachloride

Ukuhlanzeka kwezinto zokusetshenziswa, ukusatshalaliswa kwezinhlayiyana, isilinganiso sokusabalalisa ingxenye, izinga lokugeleza kwegesi ye-chlorine, idivayisi yesithando somlilo we-chlorination, izinga lokushisa lokusabela;

3.2 Ukusetshenziswa kwe-Zirconium Tetrachloride kanye Nokukhethwa Kwemikhiqizo Ephansi

I-zirconium yezinga lezimboni; I-zirconium yebanga lenuzi isiponji; I-Zirconium oxychloride; I-Yttrium zirconium powder; Ezinye izinto ze-zirconium;

533 Ukusetshenziswa okuphelele kwezinto ezilahlwayo ekukhiqizeni i-zirconium tetrachloride

3.4 Abakhiqizi be-zirconium tetrachloride

3.5 Imakethe ye-zirconium tetrachloride

3.6 Ubuchwepheshe obusha, izinto zokusebenza, nezinqubo kunqubo yokukhiqiza i-zirconium tetrachloride