1, Intangiriro ya Breif:
Ku cyumba cy'ubushyuhe,Zirconium tetrachlorideni ifu yera ya kristaline ifite imiterere ya lattice ya sisitemu ya cubic kristal.Ubushyuhe bwa sublimation ni 331 ℃ naho gushonga ni 434 ℃.Gaseous zirconium tetrachloride molekile ifite tetrahedral.Muburyo bukomeye, zirconium tetrachloride ifatanya hamwe kugirango ikore urunigi rukurikiranye hamwe na ZrCl6 octahedron nkigice.
Imiterere yimiti ya zirconium tetrachloride isa na titanium tetrachloride, ariko ibikorwa byayo bifite intege nke ugereranije na titanium tetrachloride.Zirconium tetrachloride iroroshye hydrolyz kandi irashobora kubyara zirconium oxychloride na aside hydrochloric mumazi yo mumazi cyangwa mumuyaga mwinshi.Zirconium tetrachloride irashonga mumashanyarazi menshi, nka alcool, ether, nibindi.Zirconium tetrachloride irashobora kwitwara hamwe nicyuma gikora nka sodium, magnesium, calcium, nibindi, kandi birashobora kugabanuka kubyuma cyangwa chloride nkeya bitewe nuburyo butandukanye.ZrCl4 niyo ibanziriza ibice byinshi bya zirconium.Irashobora gukoreshwa mubikorwa bitandukanye byihariye, byibanda cyane mubikoresho bya siyansi, cyangwa nkibisubizo.Irashobora kwitwara cyane hamwe namazi, ifite hygroscopique ikomeye, kandi byoroshye hydrolyzed.
Kugaragara no gusobanura:
Cas No.:10026-11-6
Zirconium tetrachlorideni umweru, urabagirana kristu cyangwa ifu ikunda gutangwa.
Izina ry'igishinwa: zirconium tetrachloride
Imiti yimiti:Zrcl4
Uburemere bwa molekuline: 233.20
Ubucucike: ubwinshi ugereranije (amazi = 1) 2.80
Umuvuduko wamazi: 0.13kPa (190 ℃)
Ingingo yo gushonga: > 300 ℃
Ingingo yo guteka: 331 ℃ / sublimation
Kamere:
Gukemura: Gushonga mumazi akonje, Ethanol, ether, kudashonga muri benzene, tetrachloride ya karubone, na karubone disulfide.Zirconium tetrachloride isohora umwotsi mu kirere cyuzuye kandi ikagira hydrolysis ikomeye iyo ihuye n’amazi.Hydrolysis ntabwo yuzuye, kandi ibicuruzwa bya hydrolysis ni zirconium oxychloride:
ZrCl4 + H2O─ → ZrOCl2 + 2HCl
2.Gushyira mubikorwa hamwe nibikorwa bya zirconium tetrachloride
Itondekanya rya zirconium tetrachloride
Urwego rwinganda rwibanze zirconium tetrachloride, urwego rwinganda rwatunganijwe zirconium tetrachloride, urwego rwa atome rwibanze rwa zirconium tetrachloride, urwego rwa atome rutunganijwe zirconium tetrachloride, hamwe na elegitoroniki ya zirconium tetrachloride.
1) Itandukaniro hagati yicyiciro cyinganda na atomic urwego zirconium tetrachloride
Urwego rwinganda zirconium tetrachloride yo gutandukanya zirconium na hafnium;Urwego rwa ingufu za atome rwa zirconium tetrachloride rwanyuze muri zirconium hafnium yo gutandukana.
2) Itandukaniro hagati ya tetrachloride ya zirconium itunganijwe neza
Zirconium tetrachloride ntisukuye kugirango ikuremo ibyuma;Zirconium tetrachloride yatunganijwe byakozwe muburyo bwo kweza no gukuraho ibyuma.
3) Icyiciro cya elegitoroniki zirconium tetrachloride
Ahanini ikoreshwa mubikorwa bya elegitoroniki.
Umusaruro wa zirconium tetrachloride
Inzira 1
Zircon sand desilication zirconia chlorination urwego rwinganda coarse zirconium tetrachloride yoza inganda urwego rwiza zirconium tetrachloride;
Inzira 2
Umucanga wa Zircon - gushonga kwa alkali - zirconium oxychloride - gutandukanya zirconium hafnium - urwego rwa atome ingufu zirconia - chlorine - urwego rwa atome ingufu za coarse zirconium tetrachloride - ingufu za atome urwego rwiza rwa zirconium tetrachloride;
Inzira 3
Umucanga wa Zircon - chlorine - urwego rwinganda coarse zirconium tetrachloride - kweza urwego rwinganda nziza zirconium tetrachloride;
Inzira 4
Umucanga wa Zircon - desilication zirconia - chlorination - urwego rwinganda rwibanze zirconium tetrachloride - kweza - urwego rwinganda rutunganijwe zirconium tetrachloride - gutandukanya pyrometallurgiki ya zirconium na hafnium - urwego rwa atome rutunganijwe zirconium tetrachloride.
Inzira 5
Umusenyi wa Zircon - chlorine - urwego rwinganda coarse zirconium tetrachloride - kweza - urwego rwinganda nziza zirconium tetrachloride Gutandukanya umuriro wa zirconium na hafnium - urwego rwa atome rwatunganijwe zirconium tetrachloride.
Ibisabwa byiza kuri zirconium tetrachloride
Ibirimo umwanda: hafnium, fer, silicon, titanium, aluminium, nikel, manganese, chromium;
Ibirimo nyamukuru: zirconi cyangwa ibyuma bya zirconi;
Isuku: 100% ukuyemo ubuziranenge bwanduye;
Ibiri mu bintu bitangirika;
Icyiciro cya elegitoroniki zirconium tetrachloride
Isuku 99,95%
Urwego rwinganda zirconium tetrachloride
1) Zirconium tetrachloride
2) Zirconium itunganijwe tetrachloride
Ingufu za Atome Urwego Zirconium Tetrachloride
1) Zirconium tetrachloride
2) Zirconium itunganijwe tetrachloride
Urwego rwibicuruzwa | Zirconium itunganijwe tetrachloride | Icyitonderwa | ||
Zr min | 37.5 | |||
Ibigize imiti (igice kinini) /% | Ibirimo umwanda ntibirenze | Al | 0.0025 | Nyuma yo kwezwa |
Fe | 0.025 | |||
Si | 0.010 | |||
Ti | 0.005 | |||
Ni | 0.002 | |||
Mn | 0.005 | |||
Cr | 0.005 |
3 Abandi
3.1 Ibintu bigira ingaruka kumusaruro wa zirconium tetrachloride
Isuku y'ibikoresho fatizo, gukwirakwiza ibice, igipimo cyo gukwirakwiza ibice, umuvuduko wa gazi ya chlorine, ibikoresho by'itanura rya chlorine, ubushyuhe bwa reaction;
3.2 Gukoresha Zirconium Tetrachloride no Guhitamo Ibicuruzwa Bimanuka
Urwego rwinganda sponge zirconium;Icyiciro cya kirimbuzi sponge zirconium;Zirconium oxychloride;Ifu ya Yttrium zirconium;Ibindi bikoresho bya zirconium;
533 Gukoresha byimazeyo ibikoresho byimyanda mugikorwa cya zirconium tetrachloride
3.4 Abakora za zirconium tetrachloride
3.5 Isoko rya zirconium tetrachloride
3.6 Ikoranabuhanga rishya, ibikoresho, nibikorwa muburyo bwo gukora zirconium tetrachloride
Igihe cyo kohereza: Gicurasi-24-2023