1,Intshayelelo emfutshane:
Kwiqondo lobushushu legumbi,Zirconium tetrachloridengumgubo omhlophe wekristale kunye nesakhiwo selattice senkqubo ye-cubic crystal. Ubushushu be-sublimation yi-331 ℃ kwaye indawo yokunyibilika yi-434 ℃. I-gaseous zirconium tetrachloride molekyuli inesakhiwo se-tetrahedral. Kwimeko eqinileyo, i-zirconium tetrachloride idibanisa omnye nomnye ukwenza i-serrated chain structure kunye ne-ZrCl6 octahedron njengeyunithi.
Iimpawu zeekhemikhali ze-zirconium tetrachloride zifana ne-titanium tetrachloride, kodwa umsebenzi wayo ubuthathaka kancinci kune-titanium tetrachloride. I-Zirconium tetrachloride i-hydrolyzed ngokulula kwaye inokuvelisa i-zirconium oxychloride kunye ne-hydrochloric acid kwizisombululo ezinamanzi okanye kumoya ofumileyo. I-Zirconium tetrachloride iyanyibilika kwii-solvents ezininzi zezinto eziphilayo, ezifana notywala, i-ether, njalo njalo. I-Zirconium tetrachloride inokusabela ngeentsimbi ezisebenzayo ezifana ne-sodium, i-magnesium, i-calcium, njl., kwaye inokwehliswa ibe yintsimbi okanye i-valent chlorides ephantsi ngokuxhomekeke kwiimeko ezahlukeneyo. I-ZrCl4 yi-precursor ye-zirconium compounds ezininzi. Ingasetyenziselwa iinjongo ezithile ezahlukeneyo, ikakhulu igxile kwisayensi yemathiriyeli, okanye njenge-catalyst. Inokusabela ngamandla ngamanzi, ine-hygroscopicity eyomeleleyo, kwaye i-hydrolyzed ngokulula.
Imbonakalo kunye neNkcazelo:
Inombolo yeCas: 10026-11-6
Zirconium tetrachlorideyikristale emhlophe, emenyezelayo okanye umgubo othanda ukuba nobuqhophololo.
Igama lesiTshayina: zirconium tetrachloride
Ifomula yemichiza:Zrcl4
Ubunzima bemolekyuli: 233.20
Uxinaniso: Uxinzelelo olunxulumeneyo (amanzi=1) 2.80
Uxinzelelo lomphunga: 0.13kPa (190 ℃)
Indawo yokunyibilika: > 300 ℃
Indawo yokubila: 331 ℃/sublimation
Indalo:
Ukunyibilika: Ukunyibilika kumanzi abandayo, i-ethanol, i-ether, into enganyibiliki kwi-benzene, i-carbon tetrachloride, kunye ne-carbon disulfide. IZirconium tetrachloride ikhupha umsi emoyeni ofumileyo kwaye ifumana ihydrolysis eyomeleleyo xa idibana namanzi. I-hydrolysis ayiphelelanga, kwaye imveliso ye-hydrolysis yi-zirconium oxychloride:
ZrCl4+H2O─→ZrOCl2+2HCl
2.Ukuhlelwa kunye nenkqubo yokuvelisa i-zirconium tetrachloride
Ukuhlelwa kwe-zirconium tetrachloride
I-Industrial grade crude zirconium tetrachloride, i-industrial grade refined zirconium tetrachloride, i-atomic level crude zirconium tetrachloride, i-atomic level refined zirconium tetrachloride, kunye ne-electron grade zirconium tetrachloride.
1) Umahluko phakathi kwebakala loshishino kunye nenqanaba le-athomu ye-zirconium tetrachloride
I-Industrial grade zirconium tetrachloride yokwahlula i-zirconium kunye ne-hafnium; Inqanaba lamandla e-athomu ye-zirconium tetrachloride liye lafumana inkqubo yokuhlukana kwe-zirconium hafnium.
2) Umahluko phakathi kwe-tetrachloride ekrwada kunye nesulungekileyo ye-zirconium
I-zirconium tetrachloride ekrwada ayizange ihlambuluke ukuze kususwe intsimbi; I-zirconium tetrachloride ecocekileyo iye yafumana inkqubo yokucoca kunye nokususa isinyithi.
3) I-Electronic grade zirconium tetrachloride
Isetyenziswa kakhulu kwishishini le-elektroniki.
Inkqubo yokuvelisa i-zirconium tetrachloride
Inkqubo 1
I-zircon isanti desilication zirconia chlorination grade coarse zirconium tetrachloride yokucoca ibakala loshishino i-zirconium tetrachloride;
Inkqubo 2
Isanti yeZircon - ukunyibilika kwe-alkali - i-zirconium oxychloride - i-zirconium hafnium yokwahlula - inqanaba le-atomic yamandla e-zirconia - i-chlorination - inqanaba le-athomu yamandla e-coarse zirconium tetrachloride - inqanaba lamandla e-athomu elungileyo zirconium tetrachloride;
Inkqubo 3
Isanti yeZircon - i-chlorination - ibakala loshishino lwe-zirconium tetrachloride - ukuhlanjululwa kwebakala loshishino oluhle lwe-zirconium tetrachloride;
Inkqubo 4
Isanti ye-Zircon - i-desilication ye-zirconia - i-chlorination - i-industrial grade crude zirconium tetrachloride - ukuhlanjululwa - i-industry grade ephuculweyo ye-zirconium tetrachloride - i-pyrometallurgical yokwahlula i-zirconium kunye ne-hafnium - inqanaba le-atomic elicocekileyo le-zirconium tetrachloride.
Inkqubo 5
Isanti ye-Zircon - i-chlorination - ibakala loshishino lwe-zirconium tetrachloride - ukuhlanjululwa - i-industrial grade fine zirconium tetrachloride Ukwahlulwa komlilo we-zirconium kunye ne-hafnium - inqanaba le-athomu elicocekileyo le-zirconium tetrachloride.
Iimfuno zomgangatho we-zirconium tetrachloride
Umxholo wokungcola: i-hafnium, isinyithi, i-silicon, i-titanium, i-aluminium, i-nickel, i-manganese, i-chromium;
Umxholo oyintloko: i-zirconia okanye i-zirconia yensimbi;
Ubunyulu: 100% thabatha ukungcola kokungcola;
Umxholo wezinto ezinganyibilikiyo;
I-Electronic grade zirconium tetrachloride
Ubunyulu 99.95%
I-Industrial grade zirconium tetrachloride
1) I-zirconium ekrwada tetrachloride
2) I-tetrachloride ecocekileyo ye-zirconium
INqanaba laMandla e-Atom iZirconium Tetrachloride
1) I-zirconium ekrwada tetrachloride
2) I-tetrachloride ecocekileyo ye-zirconium
Ibakala lemveliso | I-zirconium tetrachloride ecocekileyo | Phawula | ||
Zr min | 37.5 | |||
Ukwakheka kwemichiza (iqhezu lobunzima)/% | Umxholo wokungcola awukho mkhulu kuno | Al | 0.0025 | Emva kokuhlanjululwa |
Fe | 0.025 | |||
Si | 0.010 | |||
Ti | 0.005 | |||
Ni | 0.002 | |||
Mn | 0.005 | |||
Cr | 0.005 |
3 Abanye
3.1 Izinto ezichaphazela ukuveliswa kwe-zirconium tetrachloride
Ubunyulu bezinto eziluhlaza, ukuhanjiswa kwamasuntswana, umlinganiselo wokusasazwa kwecandelo, isantya sokuhamba kwegesi yeklorini, isixhobo somlilo se-chlorination, ubushushu bokusabela;
3.2 Ukusetyenziswa kweZirconium Tetrachloride kunye noKhetho lweeMveliso ezisezantsi
I-sponge ye-Industrial grade zirconium; Isiponji sezinga lenyukliya zirconium; iZirconium oxychloride; I-Yttrium zirconium powder; Ezinye izinto ze-zirconium;
533 Ukusetyenziswa ngokupheleleyo kwezinto ezilahlwayo kwinkqubo yokuvelisa i-zirconium tetrachloride
3.4 Abavelisi be-zirconium tetrachloride
3.5 Imarike ye-zirconium tetrachloride
3.6 Itekhnoloji entsha, izixhobo, kunye neenkqubo kwinkqubo yokuvelisa i-zirconium tetrachloride
Ixesha lokuposa: May-24-2023